A general and practical Ni-catalyzed C-H perfluoroalkylation of (hetero)arenes was written by Zhang, Shaoke;Rotta-Loria, Nicolas;Weniger, Florian;Rabeah, Jabor;Neumann, Helfried;Taeschler, Christoph;Beller, Matthias. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.Category: benzothiophene The following contents are mentioned in the article:
A direct perfluoroalkylation of (hetero)arenes using the air- and moisture-stable complex (dppf)Ni(o-tol)Cl was developed (23 examples). The novel procedure allows for the synthesis of various fluorinated products and tolerates sensitive functional groups including aldehydes, free amino groups and several heterocycles. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Category: benzothiophene).
2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Functionalized benzothiophenes are important constructs found in molecules with wide ranging biological activity and in organic materials. It has been used as a raw material for the synthesis of biologically active structures and is found in pharmaceuticals such as leukotriene synthesis inhibitors and antifungals, as well as in many natural products.Category: benzothiophene
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem