New explortion of 2,3-Dibromobenzo[b]thiophene

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Ladder-type P,S-bridged trans-stilbenes

Phosphole-containing pi-systems have emerged as building blocks with enormous potential as electronic materials because of the tunability of the phosphorus center. Among these, asymmetric P-bridged trans-stilbenes are still rare, and here an elegant and efficient synthesis toward such fluorescent molecular frameworks is described. Fine-tuning of the photophysical properties is attempted by enforcing the planarization of the phosphorus tripod and thus increasing the interaction between the phosphorus lone pair and the pi-system. The electronic structure of the pi-conjugated frameworks is analyzed with NMR, UV-vis and fluorescence spectroscopy, and time-dependent density functional theory (TD-DFT) calculations.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

Simple exploration of 2,3-Dibromobenzo[b]thiophene

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Efficient synthesis of 2,3-diarylbenzo[b]thiophene molecules through palladium (0) Suzuki?Miyaura cross-coupling reaction and their antithrombolyitc, biofilm inhibition, hemolytic potential and molecular docking studies

A series of 2,3-diaryldibenzo[b]thiophene derivatives have been synthesized via Suzuki coupling reactions in moderate to good yields (59?79%). The synthesized compounds were evaluated for their antithrombolytic, biofilm inhibition, and hemolytic potential. All compounds showed significant biological potential. Compound (4k) revealed excellent antithrombolytic (87.24%) and biofilm inhibition (99.64%) activity. While compound (4i) exhibited an outstanding hemolytic potential (84.53%). The docking studies uncovered that studied compounds interact with streptokinase and plasminogen via hydrogen bonding, pi-anion, pi?pi stacked interactions, and pi-sigma bonding type interactions. The results revealed that synthesized benzo[b]thiophene derivatives could be a potential source of therapeutic agents.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

Some scientific research about 2,3-Dibromobenzo[b]thiophene

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Ring Expansion to 6-, 7-, and 8-Membered Benzosilacycles through Strain-Release Silicon-Based Cross-Coupling

The synthesis of silacycles is highly appealing due to their important applications in organic synthesis, medicinal chemistry, and materials chemistry. However, sila-tetralins and sila-benzosuberanes are surprisingly under-represented due to a lack of general methods to access these compounds. We successfully developed a Pd-catalyzed strain-release silicon-based cross-coupling as an unprecedented ring-expansion method, which constitutes a general route for preparing diverse sila-tetralins and sila-benzosuberanes.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Synthetic Route of 6287-82-7, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 6287-82-7, molcular formula is C8H4Br2S, introducing its new discovery.

Ullmann-Type Intramolecular C-O Reaction Toward Thieno[3,2-b]furan Derivatives with up to Six Fused Rings

A new strategy for the efficient synthesis of thieno[3,2-b]benzofuran derivatives (15 examples) was achieved on the basis of successive regioselective intermolecular Suzuki and newly developed intramolecular Ullmann C-O reactions in up to a 70% overall yield. The fast intramolecular C-O reaction can be realized by an efficient catalytic combination of CuI/1,10-phenanthroline in up to a 97% yield. This method is suitable for the construction of highly fused thieno[3,2-b]furan-containing heterocycles including DTBDF and TTDBF. The pi-pi and hydrogen-bonding interactions observed for the C8-DTBDF single crystal suggest its great potential for OFET applications in the near future.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Photochemical Cycloadditions of 2,3-Dihalobenzothiophenes: Stereochemical and Mechanistic Results

Synthetic approaches to 2-thia-3,4-benzobicyclo<3.2.0>-1,3,6-heptatriene and to 2-thia-3,4-benzobicyclo<3.2.0>-1,3-heptadiene requiered halogenated cyclobutanes derived from photocycloadditions of 2,3-dichlorobenzothiophene and either vinyl bromide or 1,2-dichloroethylene.Addition reactions of vinyl bromide and dichloroethylene with 2,3-dichlorobenzothiophene and with 2,3-dibromobenzothiophene are reported.X-ray crystal structures of the two adducts derived from vinyl bromide and 2,3-dichlorobenzothiophene specify their stereochemistry.The adducts to 2,3-dibromobenzothiophene are linear, and structure determinations for these compounds are also reported.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Application of 6287-82-7, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 6287-82-7, molcular formula is C8H4Br2S, introducing its new discovery.

Toward Soluble 5,10-Diheterotruxenes: Synthesis and Reactivity of 5,10-Dioxatruxenes, 5,10-Dithiatruxenes, and 5,10-Diazatruxenes

The following work presents three general approaches allowing, for the first time, the synthesis of 5,10-diheterotruxene derivatives containing two identical heteroatoms, namely, oxygen OOC, nitrogen NNC, or sulfur SSC. Two of described pathways involve the photocyclization of the corresponding triene 2 as a key step leading to a heptacyclic aromatic system. The third approach is based on the acidic condensation between ninhydrin 14 and benzo[b]heteroole 15. Typical functionalizations of the 5,10-diheterotruxene core have also been presented. In addition, the article discusses the advantages and limitations of the three suggested paths for receiving specific 5,10-diheterotruxene derivatives because the universal method suitable for obtaining molecules with any type of heteroatoms is not known so far.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Synthesis, structure, and both cathodic and anodic reversible redox reactions of benzochalcogenophenes containing ferrocene units

2,3-Diferrocenylbenzo[b]thiophene and 1,3-diferrocenylbenzo[c]thiophene have been systematically and selectively synthesized from benzo[b]thiophene and phthaloyl dichloride, respectively. Characterization of the molecules was performed by physical and spectroscopic means and X-ray crystallographic analyses. The cyclic voltammograms of the novel thiophene derivatives containing ferrocene fragments showed a well-defined reversible cathodic step derived from the unusually stable thiophene radical anions and two distinct reversible anodic steps derived from ferrocenium cations separated from each other by a thiophene heterocycle. 1,3-Diferrocenylbenzo[c]selenophene was also synthesized in a similar manner for formation of 1,3-diferrocenylbenzo[c]thiophene by the use of bis(dimethylaluminum) selenide as a selenating reagent.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Electric Literature of 6287-82-7. In my other articles, you can also check out more blogs about 6287-82-7

Electric Literature of 6287-82-7, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 6287-82-7, Name is 2,3-Dibromobenzo[b]thiophene, molecular formula is C8H4Br2S. In a Article£¬once mentioned of 6287-82-7

Palladium-catalyzed tandem N-H/C-H arylation: Regioselective synthesis of N-heterocycle-fused phenanthridines as versatile blue-emitting luminophores

A general and highly regioselective synthetic protocol for structurally diverse N-heteroaryl-fused phenanthridines has been developed. Varieties of fluorescence molecules comprising imidazole-fused, benzoimidazole-fused, indole-fused and pyrrole-fused phenanthridines were obtained by this modular approach, some of which exhibit excellent blue-emitting performance, high quantum yields, long fluorescence lifetimes, interesting electrochemical properties, and thermal stabilities.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Synthesis and properties of symmetric and unsymmetric dibenzothienopyrroles

Symmetrical and unsymmetrical heteroacenes containing thiophene and pyrrole rings were synthesized. The unsymmetrical heteroacene was synthesized in two steps involving an unexpected palladium catalyzed amination of alkyl or aryl amines with benzo[b]thiophene followed by a copper catalyzed coupling. The symmetrical heteroacene was obtained by a palladium catalyzed amination reaction and also by a copper catalyzed amidation reaction. The crystal structure, photophysical and electrochemical properties of symmetrical and unsymmetrical heteroacenes are described.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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“Lock and key control” of photochromic reactivity by controlling the oxidation/reduction state

(Chemical Equation Presented) A photochemical active triangle terarylene was synthesized and the photochromic behavior was investigated. Its photochromic reactivity can be strongly suppressed by selected oxidization of the sulfur atoms in the molecules. Reactivated photochromic reactivity was obtained by deoxidization of the S,S-dioxide moieties. The suppressed photoactivity of the oxidation state was attributed to the stronger intramolecular hydrogen bonding interactions.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem