Category: 1086138-36-4

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Han, Zhaobin; Rong, Liangce; Wu, Jiang; Zhang, Lei; Wang, Zheng; Ding, Kuiling researched the compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine( cas:1086138-36-4 ).Reference of Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine.They published the article 《Catalytic Hydrogenation of Cyclic Carbonates: A Practical Approach from CO2 and Epoxides to Methanol and Diols》 about this compound( cas:1086138-36-4 ) in Angewandte Chemie, International Edition. Keywords: catalytic hydrogenation cyclic carbonate methanol diol production. We’ll tell you more about this compound (cas:1086138-36-4).

A highly efficient catalytic hydrogenation of cyclic carbonates was developed for the preparation of methanol with the cogeneration of the corresponding diols by using (PNP) Ru”” pincer complexes as the catalysts under relatively mild conditions. This process has provided a facile approach for the simultaneous production of two important bulk chems., methanol and EG, from ethylene carbonate, which is industrially available by reacting ethylene oxide with CO2. The coupling of the present catalytic system with the process of ethylene carbonate production in the omega process is expected to establish a new bridge from CO2 and ethylene oxide to methanol and EG. Apart from the clean production of diol, a big bonus of the present protocol is the efficient chem. utilization of CO2, which represents a distinct advantage in terms of sustainability over the omega process, which gives back CO2. Moreover, this catalytic system has also provided a potential process for the utilization of waste poly(propylene carbonate) as a resource to afford 1,2-propylene diol and methanol through hydrogenative depolymerization, and a convenient method for the preparation of deuterated methanol from CO2 and D2. A possible catalytic mechanism is proposed, in which the NH moiety of the ligand is demonstrated to be critically important in facilitating the reduction of the carbonate C=O bond through secondary coordination sphere interactions with substrates.

This compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)Reference of Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Kulkarni, Naveen V.; Brennessel, William W.; Jones, William D. researched the compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine( cas:1086138-36-4 ).Recommanded Product: 1086138-36-4.They published the article 《Catalytic Upgrading of Ethanol to n-Butanol via Manganese-Mediated Guerbet Reaction》 about this compound( cas:1086138-36-4 ) in ACS Catalysis. Keywords: catalytic upgrading ethanol butanol manganese mediated guerbet reaction. We’ll tell you more about this compound (cas:1086138-36-4).

Replacement of precious metal catalysts in the Guerbet upgrade of ethanol to n-butanol with first-row metal complex catalysts is highly appreciated due to their economic and environmental friendliness. The manganese pincer complexes of the type [(RPNP)MnBr(CO)2] (R = iPr, Cy, tBu, Ph or Ad) are found to be excellent catalysts for upgrading ethanol to n-butanol. Under suitable reaction conditions and with an appropriate base, about 34% yield of n-butanol can be obtained in high selectivity. A detailed account on the effect of the temperature, solvent, nature, and proportion of base used and the stereoelectronic effects of the ligand substituents on the catalytic activity of the catalysts as well as the plausible deactivation pathways is presented.

This compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)Recommanded Product: 1086138-36-4 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study, published in 2018-10-31, which mentions a compound: 1086138-36-4, mainly applied to aniline methanol rhenium complex catalyst selective monomethylation; methylaniline preparation, Application of 1086138-36-4.

The selective mono-N-methylation of anilines using methanol as an alkylating reagent was achieved with high efficiency under the catalysis of well-defined rhenium complexes bearing tridentate diphosphinoamino ligands and in the presence of a base. The reaction proceeds well for a large scope of anilines (32 examples) with low loadings of both the catalyst (down to 0.5 mol%) and the base (Cs2CO3, down to 5 mol%). The mechanism of the reaction was investigated by DFT (PBE0-D3) calculations

This compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)Application of 1086138-36-4 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

SDS of cas: 1086138-36-4. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine, is researched, Molecular C44H69NP2, CAS is 1086138-36-4, about Synthons for carbide complex chemistry. Author is Reinholdt, Anders; Hill, Anthony F.; Bendix, Jesper.

The sterically accessible carbide complex, (Cy3P)Cl3RuC-PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

《Synthons for carbide complex chemistry》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)SDS of cas: 1086138-36-4.

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Related Products of 1086138-36-4. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine, is researched, Molecular C44H69NP2, CAS is 1086138-36-4, about Catalytic Upgrading of Ethanol to n-Butanol via Manganese-Mediated Guerbet Reaction. Author is Kulkarni, Naveen V.; Brennessel, William W.; Jones, William D..

Replacement of precious metal catalysts in the Guerbet upgrade of ethanol to n-butanol with first-row metal complex catalysts is highly appreciated due to their economic and environmental friendliness. The manganese pincer complexes of the type [(RPNP)MnBr(CO)2] (R = iPr, Cy, tBu, Ph or Ad) are found to be excellent catalysts for upgrading ethanol to n-butanol. Under suitable reaction conditions and with an appropriate base, about 34% yield of n-butanol can be obtained in high selectivity. A detailed account on the effect of the temperature, solvent, nature, and proportion of base used and the stereoelectronic effects of the ligand substituents on the catalytic activity of the catalysts as well as the plausible deactivation pathways is presented.

《Catalytic Upgrading of Ethanol to n-Butanol via Manganese-Mediated Guerbet Reaction》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)Related Products of 1086138-36-4.

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Kulkarni, Naveen V.; Brennessel, William W.; Jones, William D. published the article 《Catalytic Upgrading of Ethanol to n-Butanol via Manganese-Mediated Guerbet Reaction》. Keywords: catalytic upgrading ethanol butanol manganese mediated guerbet reaction.They researched the compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine( cas:1086138-36-4 ).Quality Control of Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:1086138-36-4) here.

Replacement of precious metal catalysts in the Guerbet upgrade of ethanol to n-butanol with first-row metal complex catalysts is highly appreciated due to their economic and environmental friendliness. The manganese pincer complexes of the type [(RPNP)MnBr(CO)2] (R = iPr, Cy, tBu, Ph or Ad) are found to be excellent catalysts for upgrading ethanol to n-butanol. Under suitable reaction conditions and with an appropriate base, about 34% yield of n-butanol can be obtained in high selectivity. A detailed account on the effect of the temperature, solvent, nature, and proportion of base used and the stereoelectronic effects of the ligand substituents on the catalytic activity of the catalysts as well as the plausible deactivation pathways is presented.

《Catalytic Upgrading of Ethanol to n-Butanol via Manganese-Mediated Guerbet Reaction》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)Quality Control of Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine.

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Reinholdt, Anders; Hill, Anthony F.; Bendix, Jesper published an article about the compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine( cas:1086138-36-4,SMILESS:P(CCNCCP(C12CC3CC(C2)CC(C3)C1)C45CC6CC(C5)CC(C6)C4)(C78CC9CC(C8)CC(C9)C7)C%10%11CC%12CC(C%11)CC(C%12)C%10 ).Related Products of 1086138-36-4. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:1086138-36-4) through the article.

The sterically accessible carbide complex, (Cy3P)Cl3RuC-PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

Different reactions of this compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)Related Products of 1086138-36-4 require different conditions, so the reaction conditions are very important.

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine( cas:1086138-36-4 ) is researched.Recommanded Product: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine.Wei, Duo; Sadek, Omar; Dorcet, Vincent; Roisnel, Thierry; Darcel, Christophe; Gras, Emmanuel; Clot, Eric; Sortais, Jean-Baptiste published the article 《Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study》 about this compound( cas:1086138-36-4 ) in Journal of Catalysis. Keywords: aniline methanol rhenium complex catalyst selective monomethylation; methylaniline preparation. Let’s learn more about this compound (cas:1086138-36-4).

The selective mono-N-methylation of anilines using methanol as an alkylating reagent was achieved with high efficiency under the catalysis of well-defined rhenium complexes bearing tridentate diphosphinoamino ligands and in the presence of a base. The reaction proceeds well for a large scope of anilines (32 examples) with low loadings of both the catalyst (down to 0.5 mol%) and the base (Cs2CO3, down to 5 mol%). The mechanism of the reaction was investigated by DFT (PBE0-D3) calculations

Different reactions of this compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)Recommanded Product: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine require different conditions, so the reaction conditions are very important.

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Safety of Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine, is researched, Molecular C44H69NP2, CAS is 1086138-36-4, about Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study.

The selective mono-N-methylation of anilines using methanol as an alkylating reagent was achieved with high efficiency under the catalysis of well-defined rhenium complexes bearing tridentate diphosphinoamino ligands and in the presence of a base. The reaction proceeds well for a large scope of anilines (32 examples) with low loadings of both the catalyst (down to 0.5 mol%) and the base (Cs2CO3, down to 5 mol%). The mechanism of the reaction was investigated by DFT (PBE0-D3) calculations

Different reactions of this compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)Safety of Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine require different conditions, so the reaction conditions are very important.

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Formula: C44H69NP2. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine, is researched, Molecular C44H69NP2, CAS is 1086138-36-4, about Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study. Author is Wei, Duo; Sadek, Omar; Dorcet, Vincent; Roisnel, Thierry; Darcel, Christophe; Gras, Emmanuel; Clot, Eric; Sortais, Jean-Baptiste.

The selective mono-N-methylation of anilines using methanol as an alkylating reagent was achieved with high efficiency under the catalysis of well-defined rhenium complexes bearing tridentate diphosphinoamino ligands and in the presence of a base. The reaction proceeds well for a large scope of anilines (32 examples) with low loadings of both the catalyst (down to 0.5 mol%) and the base (Cs2CO3, down to 5 mol%). The mechanism of the reaction was investigated by DFT (PBE0-D3) calculations

The article 《Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study》 also mentions many details about this compound(1086138-36-4)Formula: C44H69NP2, you can pay attention to it, because details determine success or failure

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem