Addition reactions of organic carbanion equivalents via hydrazones in water was written by Wang, Yi-Zhan;Liu, Qi;Cheng, Liang;Yu, Song-Chen;Liu, Li;Li, Chao-Jun. And the article was included in Tetrahedron in 2021.Formula: C13H10OS This article mentions the following:
The addition of organometallic reagents to unsaturated bonds is one of the most powerful tools for carbon-carbon bond formations. Alkylation through organometallic reagents requires stoichiometric quantity of metal and tedious anhydrous operation in most cases. Here, “umpolung” nucleophilic additions of hydrazones to Michael acceptors, carbonyls and imines in water are reported. Under the catalysis of ruthenium(II), the addition reactions could be carried out in pure water to provide various alkylation products in moderate to good yields. In the experiment, the researchers used many compounds, for example, 3-Phenyl-1-(thiophen-2-yl)prop-2-en-1-one (cas: 3988-77-0Formula: C13H10OS).
3-Phenyl-1-(thiophen-2-yl)prop-2-en-1-one (cas: 3988-77-0) belongs to benzothiophene derivatives. Functionalized benzothiophenes are important constructs found in molecules with wide ranging biological activity and in organic materials. The different substitution patterns in these heterocycles offer new opportunities for drug discovery and other applications in materials science.Formula: C13H10OS
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem