AIBN-initiated direct thiocyanation of benzylic sp3 C-H with N-thiocyanatosaccharin was written by Wu, Di;Duan, Yongjie;Liang, Kun;Yin, Hongquan;Chen, Fu-Xue. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2021.Computed Properties of C6H8S The following contents are mentioned in the article:
A new strategy, involving a free radical reaction pathway initiated by AIBN, was used to construct the benzylic sp3 C-SCN bond. In this way, the disadvantage of other strategies involving introducing leaving groups in advance to synthesize benzyl thiocyanate compounds was avoided. The currently developed protocol also involved the use of readily available raw materials and resulted in high product yields (up to 100%), both being great advantages for synthesizing benzyl thiocyanates. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Computed Properties of C6H8S).
2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophenes are valuable heterocycles that are widely used in medicines, agrochemicals, and materials science. Due to its aromaticity, thiophenes do not exhibit the same properties as conventional thioethers.Computed Properties of C6H8S
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem