Extracurricular laboratory:new discovery of 2-Bromobenzo[b]thiophene

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Enantioselective halocyclization using reagents tailored for chiral anion phase-transfer catalysis

A chiral anion phase-transfer system for enantioselective halogenation is described. Highly insoluble, ionic reagents were developed as electrophilic bromine and iodine sources, and application of this system to o-anilidostyrenes afforded halogenated 4H-3,1-benzoxazines with excellent yield and enantioselectivity.

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Reference£º
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem