Alkali metal salts-assisted coupling reaction between fluorinated benzyl electrophiles and alkenylboronic acids was written by Xie, Wenna;Liu, Shiwen;Hammond, Gerald B.;Xu, Bo. And the article was included in New Journal of Chemistry in 2022.Computed Properties of C6H4S This article mentions the following:
Synthesis of ((aryl)trifluorobutenyl)arenes and ((aryl)fluorobutenyl)arenes (E)-ArCHR1CH:CHR [Ar = Ph, 4-ClC6H4, 3-MeOC6H4, etc.; R = Ph, 4-MeC6H4, 4-MeOC6H4, etc.; R1 = CF3, CFH2] via versatile transition metal-free cross-coupling reaction between fluorinated benzyl electrophiles and alkenylboronic acids in the presence of the equivalent amount of alkali metal salts such as K3PO4 was developed. This transition metal-free protocol gave good chem. yields for a wide range of substrates and demonstrates good functional group tolerance. In the experiment, the researchers used many compounds, for example, 2-Ethynylthiophene (cas: 4298-52-6Computed Properties of C6H4S).
2-Ethynylthiophene (cas: 4298-52-6) belongs to benzothiophene derivatives. Benzothiophenes are valuable heterocycles that are widely used in medicines, agrochemicals, and materials science. The different substitution patterns in these heterocycles offer new opportunities for drug discovery and other applications in materials science.Computed Properties of C6H4S
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem