Integrating Terminal CoBrn Salts into a 2D Cobalt(II) Coordination Polymer to Promote the β-(E)-Selective Hydroboration of Alkynes was written by Jia, Jun-Song;Wu, Tai-Xue;Fu, Yi-Jia;Hu, Zhi-Rong;Tang, Hai-Tao;Pan, Ying-Ming;Huang, Fu-Ping. And the article was included in Advanced Synthesis & Catalysis in 2022.Related Products of 4298-52-6 This article mentions the following:
In the present study, 2D Co(II) coordination polymer [[Co5(4,4′-H2dbpt)2Br10]·8(MeCOEt)]n (CP-1, 4,4′-H2dbpt = ), which integrate terminal CoBrn (CoBr2 and CoBr3) sites immobilized on the framework, are synthesized at the gram level. As a special heterogeneous catalyst, CP-1 shows regioselectivity (β:α>99:1) and stereoselectivity (only E configuration) in the hydroboration of alkynes. The hydroboration reaction conditions are mild and cover a broad substrate range (31 examples). In addition, the heterogeneous catalyst can be recycled for at least five times. In the experiment, the researchers used many compounds, for example, 2-Ethynylthiophene (cas: 4298-52-6Related Products of 4298-52-6).
2-Ethynylthiophene (cas: 4298-52-6) belongs to benzothiophene derivatives. Benzothiophene finds use in research as a starting material for the synthesis of larger, usually bioactive structures. It is also used in the manufacturing of dyes such as thioindigo.Related Products of 4298-52-6
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem