Room-Temperature Gold-Catalysed Arylation of Heteroarenes: Complementarity to Palladium Catalysis was written by Cresswell, Alexander J.;Lloyd-Jones, Guy C.. And the article was included in Chemistry – A European Journal in 2016.Product Details of 1195-14-8 This article mentions the following:
Tailoring of the pre-catalyst, the oxidant and the arylsilane enables the first room-temperature, gold-catalyzed, innate C-H arylation of heteroarenes. Regioselectivity is consistently high and, in some cases, distinct from that reported with palladium catalysis. Tolerance to halides and boronic esters, in both the heteroarene and silane partners, provides orthogonality to Suzuki-Miyaura coupling. In the experiment, the researchers used many compounds, for example, 2-Methylbenzo[b]thiophene (cas: 1195-14-8Product Details of 1195-14-8).
2-Methylbenzo[b]thiophene (cas: 1195-14-8) belongs to benzothiophene derivatives. Functionalized benzothiophenes are important constructs found in molecules with wide ranging biological activity and in organic materials. Due to its aromaticity, thiophenes do not exhibit the same properties as conventional thioethers.Product Details of 1195-14-8
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem