Synthesis of novel sensitizers with a linear conjugated di(1-benzothieno)[3,2-b:2′,3′-d]pyrrole unit for dye-sensitized solar cells was written by Zhang, Hai;Iqbal, Zafar;Chen, Zhen-E.;Hong, Yanping. And the article was included in Dyes and Pigments in 2019.Electric Literature of C8H4Br2S This article mentions the following:
Three novel D-π-A structural metal-free organic sensitizers (DBTP-1∼3) are designed, in which a linear planar aromatic group, the di(1-benzothieno)[3,2-b:2′,3′-d]pyrrole is first introduced as the π-bridge for dye-sensitized solar cells. Triphenylamine, 9,9-dimethyle-9H-fluorene and carbazole serve as the electron donor, resp., while cyanoacrylic acid is used as an electron acceptor and anchoring unit. The photophys., electrochem., theor. calculations have been employed to apprehend the correlation between the structures of DBTP-1∼3 and their photovoltaic performances. Further, co-adsorption studies are used to investigate the electronic recombination of the target dyes. As a result, the maximum power conversion efficiency of 6.50% (short-circuit current of 14.66 mA cm-2, open-circuit voltage of 0.67 V, and fill factor of 66%) for the 2 mM chenodeoxycholic acid co-adsorbed device based on DBTP-1 is obtained, while without any co-adsorbent it gives efficiency of 4.55%. The standard dye N719 gives 8.54% power conversion efficiency. In the experiment, the researchers used many compounds, for example, 2,3-Dibromobenzo[b]thiophene (cas: 6287-82-7Electric Literature of C8H4Br2S).
2,3-Dibromobenzo[b]thiophene (cas: 6287-82-7) belongs to benzothiophene derivatives. Benzothiophene is used as starting material for the synthesis of bioactive molecules. The core structure is a part of various pharmaceutical substances and natural products. It has been used as a raw material for the synthesis of biologically active structures and is found in pharmaceuticals such as leukotriene synthesis inhibitors and antifungals, as well as in many natural products.Electric Literature of C8H4Br2S
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem