Day: November 23, 2022

Meat flavor generation from different composition patterns of initial Maillard stage intermediates formed in heated cysteine-xylose-glycine reaction systems was written by Zhao, Jian;Wang, Tianze;Xie, Jianchun;Xiao, Qunfei;Du, Wenbin;Wang, Yaxin;Cheng, Jie;Wang, Shi. And the article was included in Food Chemistry in 2019.Product Details of 638-02-8 The following contents are mentioned in the article:

Volatile compounds formed in model reactions involving synthesized initial Maillard intermediates Gly-Amadori and [¹³C₅]-2-threityl-thiazolidine-4-carboxylic acids ([¹³C₅]-TTCA) in different molar ratios and free cysteine and glycine were investigated by solid-phase microextraction/gas chromatog.-mass spectrometry and gas chromatog.-olfactometry. The 1:1 ratio composition pattern provided the highest yields of all the sulfur-containing compounds, the potent meaty flavors or their ¹³C-labeled/unlabeled fractions, indicating a moderate level of glycine relative to cysteine was optimum for maximally yielding meaty flavors in complex meat-like Maillard systems containing cysteine as well as glycine. In addition, the 1:1 ratio composition led to formation of ¹³C-labeled mols. of some key meaty flavors e.g. 2-furanthiol representing over 70%, indicating TTCA/glycine reaction was better than Gly-Amadori/cysteine to yield meaty flavors. Formation pathways of twenty-nine flavors were elucidated based on the detected isotope distribution patterns. In particular, 2-methyltetrahydrothiophen-3-one, 3-thiophenethiol, 2-ethylthiophene, 2,5-dimethylthiophene, and 5-methylthiophene-2-carboxaldehyde involved a new formation pathway. Thiophene-2-carboxaldehyde and 2-methylthieno[3,2-b]thiophene showed two formation pathways. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Product Details of 638-02-8).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene scaffolds are of great importance due to its increased presence in bioactive molecules. It is also used in the manufacturing of dyes such as thioindigo.Product Details of 638-02-8

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Efficacy of some conventional fungicides and essential oils against tomato early blight disease was written by Abdel-Aty, Ahmed S.;Abdallah, Elsayed A. M.;Kaduos, Ezzat A.;Gad, Mohamed R. A.. And the article was included in World Journal of Advanced Research and Reviews in 2021.Recommanded Product: 2,5-Dimethylthiophene The following contents are mentioned in the article:

Fungicidal activity of nine selected conventional fungicides, identified five plant oils and their combined effect against A. solani, the causal pathogen of early blight on tomato. GC-MS anal. of the tested oils indicated that terpene hydrocarbons (97%) with cinnamaldehyde as the major compound; sulfur compounds; fatty acids and organo-sulfur-containing compounds were the main components in cinnamon, garlic, mustard and onion oils, resp. In vitro, Speedcide (difenoconazole) and Cabrioduo (Dimethomorph + Pyraclostrobin) were the most effective against the A. solani fungus with EC50 values of 94.6 and 88.6 ppm resp. Toledo (Tebuconzole) achieved EC50 value of 631.2 ppm. Roxyl-M was significantly more effective than Roxyl-plus or Remik. Speedcide alone or mixed with mandipropamid or azoxystrobin in Revus-Top or Cruze were the lowest effective in vitro. Garlic and mustard oils were more effective in liquid media than solid one. Cinnamon, onion, garlic and bitter almond oils caused moderate fungi-toxicity against early blight pathogen and could be implemented in the IPM program. Lower EC50 values were obtained in case of combinations of fungicides with oils than sep. treatments. Effect of the active conventional fungicides and plant oils on disease indexes, relative disease control, chlorophyll content, sugar contents and poly phenol oxidase in tomato plants was also studied. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Recommanded Product: 2,5-Dimethylthiophene).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophenes are valuable heterocycles that are widely used in medicines, agrochemicals, and materials science. It has been used as a raw material for the synthesis of biologically active structures and is found in pharmaceuticals such as leukotriene synthesis inhibitors and antifungals, as well as in many natural products.Recommanded Product: 2,5-Dimethylthiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Determination of highly volatile compounds in fresh onion (Allium cepa L.) by room-temperature enrichment headspace-trap coupled to cryotrapping GC-MS was written by Liu, Mengpan;Su, Yue;Guo, Yinlong. And the article was included in Separation Science plus in 2018.Safety of 2,5-Dimethylthiophene The following contents are mentioned in the article:

Conventional headspace-based anal. is not suitable for identifying volatile compounds in fresh onion (Allium cepa L.) because large amounts of water vapor could affect the determination of target compounds A headspace-trap was introduced to remove water vapor and keep the analytes in the trap tube. Addnl., the headspace-trap method based on room-temperature enrichment could prevent enzyme-sensitive samples from denaturing to maintain the original flavor compositions of the samples. Moreover, the highly volatile compounds were poorly separated after headspace extraction By using a cryotrapping device, these compounds were well separated Therefore, a room-temperature enrichment headspace-trap cryotrapping gas chromatog. with mass spectrometric method was established for the determination of volatile compounds in fresh onion. With this method, a total of 73 volatile compounds were identified by mass spectral search and retention index. Among them, 29 highly volatile compounds were successfully separated before the retention time of 5 min, and these compounds contributed significantly to the smell of onion. The volatile compounds were dominated by di-Pr disulfide (35.42%), 1,2-dithiolane (15.82%), 1-propanethiol (11.74%) and propanal (11.23%). The results indicated that the proposed method was an effective tool for analyzing volatile compounds in high-water-content fresh onion samples. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Safety of 2,5-Dimethylthiophene).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophenes are valuable heterocycles that are widely used in medicines, agrochemicals, and materials science. It is also used in the manufacturing of dyes such as thioindigo.Safety of 2,5-Dimethylthiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Rubber pyrolysis: Kinetic modeling and vulcanization effects was written by Liu, Sheng;Yu, Jie;Bikane, Kagiso;Chen, Tao;Ma, Chuan;Wang, Ben;Sun, Lushi. And the article was included in Energy (Oxford, United Kingdom) in 2018.Safety of 2,5-Dimethylthiophene The following contents are mentioned in the article:

Kinetic studies and the effect of the vulcanization process on the pyrolysis of natural rubber (NR), butadiene rubber (BR) and styrene-butadiene rubber (SBR) were investigated in this work. The DAEM showed a better fitting of the exptl. results than the model-based method. The activation energy distribution of the DAEM verified by the model-free method indicated that the main decomposition of rubbers followed a chain reaction mechanism. Pyrolysis of raw rubbers and their corresponding vulcanized rubbers were conducted in a fixed-bed reactor. The sulfur content and product yields were quantified. Pyrolysis oils were characterized and compared. The oil yields reached a maximum at 430°C for NR (90.82%), 470°C for both BR (90.61%) and SBR (92.80%). Pyrolytic oils of raw rubbers were mainly composed of their corresponding monomer or dimer, trimer compounds However, the results of vulcanized rubbers pyrolysis were significantly different. Sulfur in the vulcanized rubbers was released at low temperatures due to the lower bond energy. Higher temperatures led to the conversion of sulfur-containing oils to gaseous compounds Vulcanization promoted the decomposition of rubbers at low temperatures but had an insignificant influence on pyrolysis products distribution at high temperature Pyrolysis oils of vulcanized rubbers were more complex, constituting various aromatic hydrocarbons and thiophenes. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Safety of 2,5-Dimethylthiophene).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene finds use in research as a starting material for the synthesis of larger, usually bioactive structures. Due to its aromaticity, thiophenes do not exhibit the same properties as conventional thioethers.Safety of 2,5-Dimethylthiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem