Synthesis and complexation behavior of 3,4-bis(chloromercurio)2,5-dimethylthiophene was written by Sa, Shreenibasa;Sathesh, Venkatesan;Murali, Anna Chandrasekar;Nayak, Prakash;Venkatasubbaiah, Krishnan. And the article was included in Journal of Organometallic Chemistry in 2021.Synthetic Route of C6H8S The following contents are mentioned in the article:
Synthesis of a new bidentate Lewis acid 3,4-bis(chloromercurio)2,5-dimethylthiophene (1) has been reported which is not accessible using other methods. Crystallization of compound 1 from a THF (THF) and DMSO (DMSO) results Lewis acid-nucleophile (Lewis base) adduct in 1:2 ratio such as C6H6SHg2Cl2•2THF (2) & C6H6SHg2Cl2•2DMSO (3) resp. The bifunctional Lewis acid on crystallization with Et4NCl resulted in the formation of compound 4 {[(C6H6SHg2Cl2)3Cl2][Et4N]2}, which is a unique 3:2 adduct of compound 1 with chloride anion. Compounds 1–4 have been characterized by NMR, elemental anal., and X-ray crystallog. The solid state structures of compounds 1–4 reveals the existence of Hg•••Cl, C-H•••Cl weak interactions which lead to the formation of 1D, 2D and 3D supramol. structures. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Synthetic Route of C6H8S).
2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophenes are valuable heterocycles that are widely used in medicines, agrochemicals, and materials science. Due to its aromaticity, thiophenes do not exhibit the same properties as conventional thioethers.Synthetic Route of C6H8S
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem