Day: November 22, 2022

Catalytic Synthesis of Methylthiophenes was written by Mashkina, A. V.;Khairulina, L. N.. And the article was included in Russian Journal of Organic Chemistry in 2018.Computed Properties of C6H8S The following contents are mentioned in the article:

The gas-phase reaction of di-Me disulfide with thiophene over Co/HZSM-5 catalyst in a helium medium under atm. pressure at 250-350° gave a mixture of mono-, di-, tri- and tetramethylthiophenes with an overall selectivity of 94-96%. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Computed Properties of C6H8S).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophenes are valuable heterocycles that are widely used in medicines, agrochemicals, and materials science. It is found within the chemical structures of pharmaceutical drugs such as raloxifene, zileuton, sertaconazole, and also BTCP.Computed Properties of C6H8S

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

TfOH-Catalyzed Reaction between 3-Diazoindolin-2-imines and Electron-Rich Arenes: Access to 3-Aryl-2-aminoindoles was written by Qi, Jie;Wang, Zaibin;Lang, Bo;Lu, Ping;Wang, Yanguang. And the article was included in Journal of Organic Chemistry in 2017.Product Details of 638-02-8 The following contents are mentioned in the article:

TfOH-catalyzed reactions between 3-diazoindolin-2-imines and electron-rich arenes were disclosed. These metal-free reactions furnished 3-aryl-2-aminoindoles in moderate to excellent yields with the tolerance of a broad range of functional groups. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Product Details of 638-02-8).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene is a fused ring compound of thiophene ring and benzene ring, which is an important class of heterocycles with advantageous structures. Its aromaticity makes it relatively stable, although as a heterocycle, it has reactive sites which allow for functionalization.Product Details of 638-02-8

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Tetrahydrobenzothiophene inhibitors of hepatitis C virus NS5B polymerase was written by LaPorte, M. G.;Lessen, T. A.;Leister, L.;Cebzanov, D.;Amparo, E.;Faust, C.;Ortlip, D.;Bailey, T. R.;Nitz, T. J.;Chunduru, S. K.;Young, D. C.;Burns, C. J.. And the article was included in Bioorganic & Medicinal Chemistry Letters in 2006.Recommanded Product: 95211-67-9 The following contents are mentioned in the article:

A novel series of selective HCV NS5B RNA dependent RNA polymerase inhibitors has been disclosed. These compounds contain an appropriately substituted tetrahydrobenzothiophene scaffold. This communication will detail the SAR and activities of this series. This study involved multiple reactions and reactants, such as Ethyl 2-amino-4-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate (cas: 95211-67-9Recommanded Product: 95211-67-9).

Ethyl 2-amino-4-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate (cas: 95211-67-9) belongs to benzothiophene derivatives. Benzothiophene finds use in research as a starting material for the synthesis of larger, usually bioactive structures. The different substitution patterns in these heterocycles offer new opportunities for drug discovery and other applications in materials science.Recommanded Product: 95211-67-9

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Switching of the π-electronic conjugations in the reduction of a dithienylethene-fused p-benzoquinone was written by Saito, Eiji;Ako, Takumi;Kobori, Yasuhiro;Tsuda, Akihiko. And the article was included in RSC Advances in 2017.Application In Synthesis of 2,5-Dimethylthiophene The following contents are mentioned in the article:

The electron accepting character of a dithienylethene-fused p-benzoquinone derivative is significantly reduced upon ring-closing isomerization. Visible light unlocks the π-electronic conjugation of the quinone so it can be utilized for a light-driven oxidation reaction. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Application In Synthesis of 2,5-Dimethylthiophene).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene is relatively a stable molecule. The core structure is a part of various pharmaceutical substances and natural products. It is found within the chemical structures of pharmaceutical drugs such as zileuton, raloxifene, and sertaconazole, and also BTCP.Application In Synthesis of 2,5-Dimethylthiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

From One-Pot NH-Sulfoximidations of Thiophene Derivatives to Dithienylethene-Type Photoswitches was written by Verbelen, Bram;Siemes, Eric;Ehnbom, Andreas;Raeuber, Christoph;Rissanen, Kari;Woell, Dominik;Bolm, Carsten. And the article was included in Organic Letters in 2019.Computed Properties of C6H8S The following contents are mentioned in the article:

Thiophene NH-sulfoximines were synthesized using a 1-pot NH-sulfoximidation reaction of thiophenes. The reactivity of the products was studied, and the developed protocols were used for the synthesis of a new class of dithienylethene-type photoswitches containing a sulfoximidoyl group. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Computed Properties of C6H8S).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Functionalized benzothiophenes are important constructs found in molecules with wide ranging biological activity and in organic materials. The different substitution patterns in these heterocycles offer new opportunities for drug discovery and other applications in materials science.Computed Properties of C6H8S

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

A general and practical Ni-catalyzed C-H perfluoroalkylation of (hetero)arenes was written by Zhang, Shaoke;Rotta-Loria, Nicolas;Weniger, Florian;Rabeah, Jabor;Neumann, Helfried;Taeschler, Christoph;Beller, Matthias. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.Category: benzothiophene The following contents are mentioned in the article:

A direct perfluoroalkylation of (hetero)arenes using the air- and moisture-stable complex (dppf)Ni(o-tol)Cl was developed (23 examples). The novel procedure allows for the synthesis of various fluorinated products and tolerates sensitive functional groups including aldehydes, free amino groups and several heterocycles. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Category: benzothiophene).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Functionalized benzothiophenes are important constructs found in molecules with wide ranging biological activity and in organic materials. It has been used as a raw material for the synthesis of biologically active structures and is found in pharmaceuticals such as leukotriene synthesis inhibitors and antifungals, as well as in many natural products.Category: benzothiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Towards a practical perfluoroalkylation of (hetero)arenes with perfluoroalkyl bromides using cobalt nanocatalysts was written by Zhang, Shaoke;Weniger, Florian;Kreyenschulte, Carsten Robert;Lund, Henrik;Bartling, Stephan;Neumann, Helfried;Ellinger, Stefan;Taeschler, Christoph;Beller, Matthias. And the article was included in Catalysis Science & Technology in 2020.Application In Synthesis of 2,5-Dimethylthiophene The following contents are mentioned in the article:

A convenient methodol. for perfluoroalkylation including trifluoromethylation of (hetero)arenes with perfluoroalkyl bromides was developed. Key for the success is the use of a specific cobalt-based nanocatalyst, which can be recycled at least up to 4 times. The scope of this first cobalt-catalyzed perfluoroalkylation is presented. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Application In Synthesis of 2,5-Dimethylthiophene).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene is a fused ring compound of thiophene ring and benzene ring, which is an important class of heterocycles with advantageous structures. Due to its aromaticity, thiophenes do not exhibit the same properties as conventional thioethers.Application In Synthesis of 2,5-Dimethylthiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Iron-catalyzed Versatile and Efficient C(sp²)-H Borylation was written by Kamitani, Masahiro;Kusaka, Haruki;Yuge, Hidetaka. And the article was included in Chemistry Letters in 2019.Category: benzothiophene The following contents are mentioned in the article:

The efficient C-H borylation of a variety of aromatic hydrocarbons and heteroarenes has been achieved using an iron complex bearing a quinoline-based PNN pincer ligand. Mechanistic studies revealed the formation of a bis-boryl complex, which plays a crucial role in the catalytic cycle. The methodol. allows the borylation of unactivated arenes using iron catalysts. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Category: benzothiophene).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Functionalized benzothiophenes are important constructs found in molecules with wide ranging biological activity and in organic materials. It is found within the chemical structures of pharmaceutical drugs such as zileuton, raloxifene, and sertaconazole, and also BTCP.Category: benzothiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

A solvent less synthesis of 2-aminothiophenes via the Gewald reaction under ultrasonic conditions was written by de C. F. dos Santos, Bruno Dias;Forero, Josue S. Bello;de Carvalho, Erika M.;Jones, Joel Jr.;da Silva, Flavia M.. And the article was included in Heterocyclic Letters in 2012.Category: benzothiophene The following contents are mentioned in the article:

A simple, fast and efficient one-pot, three-component, solvent less procedure for the synthesis of 2-aminothiophene derivatives under ultrasonic conditions was developed. The combined advantages of sonochem., such as mild reaction conditions, good yield and short reaction times, enabled progress to be made on the synthesis of 2-aminothiophenes via the Gewald reaction. This study involved multiple reactions and reactants, such as Ethyl 2-amino-4-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate (cas: 95211-67-9Category: benzothiophene).

Ethyl 2-amino-4-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate (cas: 95211-67-9) belongs to benzothiophene derivatives. Benzothiophene is a fused ring compound of thiophene ring and benzene ring, which is an important class of heterocycles with advantageous structures. It is found within the chemical structures of pharmaceutical drugs such as zileuton, raloxifene, and sertaconazole, and also BTCP.Category: benzothiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Rhodium-catalyzed cycloisomerization of ester-tethered 1,6-diynes with cyclopropanol moiety leading to tetralone/exocyclic diene hybrid molecules was written by Yasui, Takeshi;Kikuchi, Tomohiro;Yamamoto, Yoshihiko. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2020.Application In Synthesis of 2,5-Dimethylthiophene The following contents are mentioned in the article:

The rhodium-catalyzed cycloisomerization of ester-tethered 1,6-diynes bearing a cyclopropanol moiety produced tetralone/exocyclic diene hybrid mols. with thermodynamically unfavorable alkene geometry. The results of control experiments and d. functional theory calculations suggest that the ester tether plays an important role in the efficiency of E/Z isomerization processes. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Application In Synthesis of 2,5-Dimethylthiophene).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Functionalized benzothiophenes are important constructs found in molecules with wide ranging biological activity and in organic materials. Its aromaticity makes it relatively stable, although as a heterocycle, it has reactive sites which allow for functionalization.Application In Synthesis of 2,5-Dimethylthiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem