Raju, Telugu Bhim published the artcileHighly efficient and facile alkylation of 4H-cyclopenta-[2,1-b:3,4-b’]dithiophene in water, Safety of 2,6-Dibromo-4,4-bis(6-bromohexyl)-4H-cyclopenta[1,2-b:5,4-b’]dithiophene, the publication is RSC Advances (2014), 4(71), 37738-37745, database is CAplus.
A new and highly convenient method to perform alkylation of 4H-cyclopenta-[2,1-b:3,4-b’]dithiophene (CPDT) in aqueous conditions is reported. This method was also extended to successfully perform alkylation of 2,6-dibromo-4H-cyclopenta-[2,1-b:3,4-b’]dithiophene for the first time. This facile method has several advantages such as the exclusive use of water instead of high boiling toxic solvents, simple separation of the defect free dialkylated CPDT product I (Y = H, Br; R = hexyl, octyl, 5-bromopentyl, etc.) and the use of mild reaction conditions. Despite using mild reagents and reaction conditions, very high yields of up to 98% pure dialkylated CPDT products I are obtained much more readily by this method in less time than literature procedures. The desired dialkylated product with the alkyl halides used here.
RSC Advances published new progress about 1426829-76-6. 1426829-76-6 belongs to benzothiophene, auxiliary class Other Aromatic Heterocyclic,Bromide, name is 2,6-Dibromo-4,4-bis(6-bromohexyl)-4H-cyclopenta[1,2-b:5,4-b’]dithiophene, and the molecular formula is C21H26Br4S2, Safety of 2,6-Dibromo-4,4-bis(6-bromohexyl)-4H-cyclopenta[1,2-b:5,4-b’]dithiophene.
Referemce:
https://en.wikipedia.org/wiki/Benzothiophene,
Benzothiophene | C8H6S – PubChem