Rastogi, Gaurav K. published the artcileVisible-Light-Driven Z -Selective Reaction of Methyl Ketones with DMSO: A Mild Synthetic Approach to Methylthio-Substituted 1,4-Enedione Promoted by Selectfluor, Synthetic Route of 1468-83-3, the main research area is methylthio enedione preparation diastereoselective photochem; methyl ketone dimethyl sulfoxide Kornblum reaction aldol.
Here a simple, visible-light-driven Z-selective synthesis of methylthio-substituted 1,4-enediones I (Ar = C6H5, 3-ClC6H4, 2-furyl, etc.) in a single step promoted by Selectfluor is disclosed. DMSO is used as both the ‘thio’ source and the solvent. Mol. iodine and potassium persulfate are used as catalyst and oxidant, resp. White light (CFL-30W) is used as the light source. The proposed mechanism involves a Kornblum reaction followed by aldol reaction.
Synthesis published new progress about Aldol condensation catalysts, stereoselective. 1468-83-3 belongs to class benzothiophene, name is 3-Acetylthiophene, and the molecular formula is C6H6OS, Synthetic Route of 1468-83-3.
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem