Cui, Jianguo’s team published research in Tetrahedron in 2020-03-06 | CAS: 1468-83-3

Tetrahedron published new progress about Keto esters Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 1468-83-3 belongs to class benzothiophene, name is 3-Acetylthiophene, and the molecular formula is C6H6OS, Application In Synthesis of 1468-83-3.

Cui, Jianguo published the artcileOxidative umpolung selenocyanation of ketones and arenes: An efficient protocol to the synthesis of selenocyanates, Application In Synthesis of 1468-83-3, the main research area is ketone potassium selenocyanate oxidative umpolung selenocyanation; keto ester potassium selenocyanate oxidative umpolung selenocyanation; arene potassium selenocyanate regioselective oxidative umpolung selenocyanation.

A practical method for the umpolung selenocyanation of aryl ketones, alkyl ketones, β-ketoesters and electron-rich arenes was developed, afforded various selenocyanates in moderate to excellent yields. This transformation proceeded by an oxidative umpolung selenocyanation through nitrogen oxides-mediated electrophilic selenocyanation process. This method is simpler, more efficient, and less costly than precedent methods. Further transformations of the arylselenocyanate was performed to prove the synthetic utility of this methodol.

Tetrahedron published new progress about Keto esters Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 1468-83-3 belongs to class benzothiophene, name is 3-Acetylthiophene, and the molecular formula is C6H6OS, Application In Synthesis of 1468-83-3.

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem