《A metal-free heterogeneous photocatalyst for the selective oxidative cleavage of C=C bonds in aryl olefins via harvesting direct solar energy》 was written by Zhang, Yu; Hatami, Nareh; Lange, Niklas Simon; Ronge, Emanuel; Schilling, Waldemar; Jooss, Christian; Das, Shoubhik. Computed Properties of C6H6OS And the article was included in Green Chemistry in 2020. The article conveys some information:
A mild and efficient protocol was developed using polymeric carbon nitrides (PCN) as metal-free heterogeneous photocatalysts to convert various olefins into the corresponding carbonyls such as R1C(O)R2 [R1 = Ph, 4-MeC6H4, 2-pyridyl, etc.; R2 = H, Me, Ph, etc.]. Later, this catalyst was applied in the gram scale synthesis of pharmaceutical drugs using direct solar energy. Detailed mechanistic studies revealed the actual role of oxygen, the catalyst and the light source. In the part of experimental materials, we found many familiar compounds, such as 1-Thiophen-2-yl-ethanone(cas: 88-15-3Computed Properties of C6H6OS)
1-Thiophen-2-yl-ethanone(cas: 88-15-3) belongs to thiophenes. Reflecting their high stabilities, thiophenes arise from many reactions involving sulfur sources and hydrocarbons, especially unsaturated ones. Thiophenes are classically prepared by the reaction of 1,4-diketones, diesters, or dicarboxylates with sulfidizing reagents such as P4S10 such as in the Paal-Knorr thiophene synthesis. Computed Properties of C6H6OS
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem