《Base-free oxidation of alcohols enabled by nickel(II)-catalyzed transfer dehydrogenation》 was written by Ye, Danfeng; Liu, Zhiyuan; Sessler, Jonathan L.; Lei, Chuanhu. Quality Control of 1-Thiophen-2-yl-ethanone And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2020. The article conveys some information:
An efficient nickel(II)-catalyzed transfer dehydrogenation oxidation of alcs. was reported that relies on cyclohexanone as the formal oxidant and does not require the use of an external base. The synthetic utility of this protocol was demonstrated via the facile oxidation of structurally complicated natural products. After reading the article, we found that the author used 1-Thiophen-2-yl-ethanone(cas: 88-15-3Quality Control of 1-Thiophen-2-yl-ethanone)
1-Thiophen-2-yl-ethanone(cas: 88-15-3) belongs to thiophenes. Reflecting their high stabilities, thiophenes arise from many reactions involving sulfur sources and hydrocarbons, especially unsaturated ones. Thiophenes are classically prepared by the reaction of 1,4-diketones, diesters, or dicarboxylates with sulfidizing reagents such as P4S10 such as in the Paal-Knorr thiophene synthesis. Quality Control of 1-Thiophen-2-yl-ethanone
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem