So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Kulkarni, Naveen V.; Brennessel, William W.; Jones, William D. researched the compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine( cas:1086138-36-4 ).Recommanded Product: 1086138-36-4.They published the article 《Catalytic Upgrading of Ethanol to n-Butanol via Manganese-Mediated Guerbet Reaction》 about this compound( cas:1086138-36-4 ) in ACS Catalysis. Keywords: catalytic upgrading ethanol butanol manganese mediated guerbet reaction. We’ll tell you more about this compound (cas:1086138-36-4).
Replacement of precious metal catalysts in the Guerbet upgrade of ethanol to n-butanol with first-row metal complex catalysts is highly appreciated due to their economic and environmental friendliness. The manganese pincer complexes of the type [(RPNP)MnBr(CO)2] (R = iPr, Cy, tBu, Ph or Ad) are found to be excellent catalysts for upgrading ethanol to n-butanol. Under suitable reaction conditions and with an appropriate base, about 34% yield of n-butanol can be obtained in high selectivity. A detailed account on the effect of the temperature, solvent, nature, and proportion of base used and the stereoelectronic effects of the ligand substituents on the catalytic activity of the catalysts as well as the plausible deactivation pathways is presented.
This compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)Recommanded Product: 1086138-36-4 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem