Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 3395-91-3, is researched, SMILESS is O=C(OC)CCBr, Molecular C4H7BrO2Journal, Synlett called Electrochemical Synthesis of 2-Bromoethyl and 2-Iodoethyl Ketones from Cyclopropanols, Author is Barysevich, Maryia V.; Aniskevich, Yauhen M.; Hurski, Alaksiej L., the main research direction is haloalkyl ketone preparation; alkyl cyclopropanol magnesium halide electrochem regioselective ring opening halogenation.Synthetic Route of C4H7BrO2.
A simple electrochem. protocol for the preparation of 2-bromoethyl- and 2-iodoethyl ketones from cyclopropanols and magnesium halides were developed. The reaction proceeded with exclusive regioselectivity and without epimerization of the α-stereocenter in the products. The synthesized diastereomerically pure 2-bromoethyl ketones underwent smooth copper and nickel-catalyzed alkylation, alkenylation, and arylations reactions.
This compound(Methyl 3-bromopropanoate)Synthetic Route of C4H7BrO2 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem