The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine( cas:1086138-36-4 ) is researched.Recommanded Product: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine.Wei, Duo; Sadek, Omar; Dorcet, Vincent; Roisnel, Thierry; Darcel, Christophe; Gras, Emmanuel; Clot, Eric; Sortais, Jean-Baptiste published the article 《Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study》 about this compound( cas:1086138-36-4 ) in Journal of Catalysis. Keywords: aniline methanol rhenium complex catalyst selective monomethylation; methylaniline preparation. Let’s learn more about this compound (cas:1086138-36-4).
The selective mono-N-methylation of anilines using methanol as an alkylating reagent was achieved with high efficiency under the catalysis of well-defined rhenium complexes bearing tridentate diphosphinoamino ligands and in the presence of a base. The reaction proceeds well for a large scope of anilines (32 examples) with low loadings of both the catalyst (down to 0.5 mol%) and the base (Cs2CO3, down to 5 mol%). The mechanism of the reaction was investigated by DFT (PBE0-D3) calculations
Different reactions of this compound(Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine)Recommanded Product: Bis(2-(Di(adamantan-1-yl)phosphino)ethyl)amine require different conditions, so the reaction conditions are very important.
Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem