Chemical Research in 3395-91-3

Here is just a brief introduction to this compound(3395-91-3)COA of Formula: C4H7BrO2, more information about the compound(Methyl 3-bromopropanoate) is in the article, you can click the link below.

COA of Formula: C4H7BrO2. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Methyl 3-bromopropanoate, is researched, Molecular C4H7BrO2, CAS is 3395-91-3, about Asymmetric α-alkylation of cyclic β-keto esters and β-keto amides by phase-transfer catalysis. Author is Wang, Yakun; Li, Yueyun; Lian, Mingming; Zhang, Jixia; Liu, Zhaomin; Tang, Xiaofei; Yin, Hang; Meng, Qingwei.

Without employing any transition metal, a highly enantioselective α-alkylation of cyclic β-keto esters and β-keto amides has been realized by phase-transfer catalysis. This improved procedure is applicable to different kinds of bromides with cinchona derivatives and gives the corresponding products e.g., I and e.g., II, in excellent enantiopurities (up to 98% ee) and good yields (up to 98%). Moreover, the reaction was scalable and the phase-transfer catalyst was recyclable. This provided an alternative and competitive method to the asym. α-alkylation of β-dicarbonyl compounds

Here is just a brief introduction to this compound(3395-91-3)COA of Formula: C4H7BrO2, more information about the compound(Methyl 3-bromopropanoate) is in the article, you can click the link below.

Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem