Application of 3395-91-3. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Methyl 3-bromopropanoate, is researched, Molecular C4H7BrO2, CAS is 3395-91-3, about Cobalt(I)-Catalyzed Borylation of Unactivated Alkyl Bromides and Chlorides. Author is Verma, Piyush Kumar; Prasad, K. Sujit; Varghese, Dominic; Geetharani, K..
A Co-complex-catalyzed borylation of a wide range of alkyl halides with a diboron reagent (B2pin2 or B2neop2) was developed under mild reaction conditions, demonstrating the 1st Co-mediated cross-coupling with alkyl electrophiles. This protocol allows alkyl boronic esters to be accessed from alkyl halides, including alkyl chlorides, which were used rarely as coupling partners. Mechanistic studies reveal the possible involvement of an alkyl radical intermediate in this Co-mediated catalytic cycle.
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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem