Electric Literature of 19301-35-0, When developing chemical systems it’s of course important to gain a deep understanding of the chemical reaction process. In a article, 19301-35-0, molcular formula is C8H6OS, introducing its new discovery.
A novel method for Pd-catalyzed triflination of aryl and heteroaryl triflates using NaSO2CF3 as the nucleophile is described. The combination of Pd2(dba)3 and RockPhos formed the most effective catalyst. A broad range of functional groups and heteroaromatic compounds were tolerated under the neutral reaction conditions. The order of reactivity ArOTf ? ArCl ? ArBr is consistent with transmetalation being a slow step of the reaction.
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Reference：
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem