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The synthesis of a variety of 2-(haloethenyl)benzothiophenes from both substituted and unsubstituted benzothiophenes is described.Their corresponding 1,1-dioxides exhibited versatile reactivity via addition/conjugated elimination and direct substitution mechanisms with amine,thio, and alkoxy nucleophiles in good yield
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Reference：
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem