New explortion of Methyl benzo[b]thiophene-2-carboxylate

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The dynamic chemical diversity of the numerous elements, ions and molecules that constitute the basis of life provides wide challenges and opportunities for research. 22913-24-2, In an article, mentioned the application of 22913-24-2, Name is Methyl benzo[b]thiophene-2-carboxylate, molecular formula is C10H8O2S

The invention relates to ruthenium catalytic ester derivative selective dehydrogenation boron reaction new method, including falling to six coordination of borneol diene (NBD) ligand of ruthenium complex as catalyst, in order to methyl ester derivatives and joint frequency which mellow boron ester is the reaction substrate, the reaction under mild conditions, the high-efficient catalytic ester derivative in an oxygen atom ortho-methyl-hydrogen bond selectively generating boron reaction, to obtain the corresponding methyl ester borate product. At present, in the ester derivatives on the oxygen atom ortho-methyl hydrogen bond of boron selective dehydrogenation reaction has not yet been reported. The invention realized for the first time the occurrence of the oxygen atom of the ester derivative selective ortho-methyl of the dehydrogenation boron reaction, as the organic ester borate such organic synthetic intermediates preparation provides a new response strategies. (by machine translation)

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem