Reference of 5394-13-8, New research progress on 5394-13-8 in 2021. Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. In a article, 5394-13-8, molcular formula is C8H5BrS, introducing its new discovery.
A mononuclear iron complex with 2-ethynylbenzo[b]thiophene C-coordinated to the (eta5-Cp*)(eta2-dppe)Fe (Cp* = pentamethylcyclopentadienyl, dppe = 1,2-diphenylphosphinoethane) framework (1) was prepared and characterized by 1H NMR, elemental analysis, and single crystal X-ray diffraction. The redox behavior of 1 was investigated by voltammetric methods and anodic spectroelectrochemistry in the UV?vis-NIR-IR region and compared with reference complexes including 2-ferrocenylbenzo[b]thiophene (2) and the 2-ethynylpyridine derivative of 1. The spin density distribution along the linear molecular backbone in 1+ was analyzed by DFT (BLYP35) and TDDFT calculations of a truncated model complex. The combined experimental and theoretical results revealed an important role of the ethynylene linker in determining the redox properties of this family of complexes and participation of the 2-ethynylbenzo[b]thiophene framework in the largely iron-based anodic electron transfer.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 5394-13-8
Reference：
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem