Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. Recommanded Product: 5-Bromobenzothiophene, In an article, mentioned the application of 4923-87-9, Name is 5-Bromobenzothiophene, molecular formula is C8H5BrS
Step-Edge Assisted Direct Linear Alkane Coupling
Direct coupling of alkanes via C?H activation of terminal methyl groups has acquired tremendous interests both scientifically and technically. Herein we present the results of linear alkane-coupling at the step edges of Cu surfaces at modulated temperatures. Combining the observations of scanning tunneling microscopy (STM) with density functional theory plus dispersion (DFT-D) calculations, we elucidate the mechanism of the reaction and demonstrate that the low activation barrier relies on heterogeneous catalysis at the upper step edges, where low-coordinated surface atoms are present. We further reveal the generality of the reaction, so that it can be applied on the step edges of different facets of surfaces.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Recommanded Product: 5-Bromobenzothiophene, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 4923-87-9, in my other articles.
Reference£º
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem